Friday Sep 03

Grading

Opal Identification

 

opal identification opal identification

GEMMOLOGICAL LABORATORY FACT SHEET:

Chemical composition of Opal:

Si02nH20 – Hydrated Silica.

• Water content in Precious Opal 3-10%.

• Water content in Potch or Common Opal 2-20%

• Impurities are Oxides of:

Aluminium (~2.5%), Calcium (~1%), Sodium (~0.4%), Iron (~0.3%), Titanium and Magnesium (~0.1%) and in much smaller traces Zirconia, Manganese, Copper, Nickel and Cobalt.


Chemical composition of Boulder Opal:

SiO2 at 28%, Fe2O3 + Al2O3 at 68%, H20 at 4% approximately.

Hardness on Mohs Scale 1-10:

Opal is 5.5 to 6.5 on the Mohs Scale (Note* A relative not an absolute scale)

Scratch
Hardness
(Mohs)
Mineral used
for resistance
Comparison
Simple Hardness
tester
Cutting
1 Talc Can be scratched with fingernail 0.03
2 Gypsum Can be scratched with fingernail 1.25
3 Pearl, Bone
Can be scratched with copper coin 4.5
4 Fluorite, Marble Easily scratched with knife
5.0
5 Glass, Obsidian Can be scratched with knife
6.5
6 Opal, Turquoise, Garnet Can be scratched with steel file 37
7 Quartz,Tourmaline Scratches window glass 120
8 Topaz, Aquamarine Can be scratched with corundum 175
9 Sapphire, Ruby Can be scratched with diamond 1,000
10 Diamond Can be scratched with diamond 140,000


Specific Gravity (SG):

 
• White or Black Opal 2.10-2.30
• Boulder Opal 2.60-2.80

Note* SG indicates the relation between the measured gemstone and an equal amount of water, its numerical value is between 1 and 8, values under 2 are considered light, those from 2 to 4 normal and over 4 heavy.

Cleavage:


• None in White or Black Opal.

• Distinct in Boulder Opal which may split along an Opal vein to produce two faces of Opal, due to the angle of the Opal vein’s microstructure growth in the cavity.

Referred to as 'Splits' or a 'Split Pair'. When inherent veins are true, fairly flat and straight and the splitting operation is performed by an expert lapidary Opal will remain entirely adhered to both sides of the host rock.

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Fracture: Conchoidal (glass-like)

Lustre: Vitreous (glass-like)

Streak:

• White or colourless for White or Black Opal
• White or colourless on the top-side and brown on the bottom-side for Boulder Opal  

Diaphaneity: Transparent, translucent and opaque

Optic Character: Opal is a singly refractive gem. Light which enters an Opal remains as non-polarized beams, and travels through all directions of the stone at the same speed.

Refractive Index (RI): 1.37 – 1.47; Opal has no birefringence, each one has a single RI figure in this range.

Pleochroism: None.

Note* Pleochroism is caused by the double refraction of light and should not be confused with the play of colour which characterises Opal.

Crystal System:
Opal is an Amorphous mineral, it does not occur in a particular crystallographic form. It is a replacement mineral which occurs in veins, nodules and fossils. Potch or common Opal does not have an orderly atomic structure, only precious Opal has a regular internal structure.

Atomic Structure: Electron microscope Studies (40,000x magnification) have revealed Opal is composed of tiny spheres of transparent hard silica, 0.01 to 0.0005 mm in diameter, sitting in a bath of hydrous silica.

refraction_grating.jpg

Light passes through the spheres in a straight line but when it hits the spaces between the spheres, containing silica in solution; it is bent and deflected at different angles. The overall effect of the silica arrangement is to produce a diffraction grating which breaks up white light into its constituent parts producing the visual phenomenon known as ‘play of colour’. According to the sizes of the spheres, varying colours of the spectrum are diffracted. Red colour is attributed to larger spheres ~4000 Å in diameter, while green opal spheres are ~2500 Å. Note*(Angstrom units; 1 Å = 10 -7mm) The size of the spheres diminishes through the spectrum; RED_ORANGE_YELLOW_GREEN_BLUE_INDIGO_VIOLET. Violet is attributed to the smallest spheres.

Electron micrographs:

precious_opal_under_electron_microscope.jpg potch_under_electron_microscope.jpg
Precious Opal

Common Opal

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In precious opal the spheres are uniformly sized and arranged in an orderly 3 dimensional grid, whereas in common opal the spheres vary in size and shape, discovered by Australian CSIRO scientists Darragh and Sanders in 1965.

Field Observation: Opal seams generally show a layered structure similar to the horizontal bedding in its sedimentary host rock. Layers may differ from adjacent layers in body colour, transparency, or colour patterns.

Luminescence (Fluorescence & Phosphorescence): Black and Boulder Opal do not fluoresce. Crystal and Light Opal, mostly from South Australia, fluoresce a cloudy white under U.V. light. This is followed by a rather prolonged phosphorescent afterglow. This afterglow is hardly perceptible in Gilson Light Opal.

Opalescence: The milky-blue or pearly appearance of common opal, opalescent glass and moonstone is caused by internal reflection of short wave, mainly blue light. This optical effect is due to the scattering of light by particles of matter in its path, such as is caused by a ray of light illuminating dust particles in the air of a room. Opalescence should not be confused with play of colour.

Chatoyancy: The Cat’s eye effect is caused by the reflection of light from multiple parallel needles or fibres which are inclusions in the stone. This phenomenon is most effective when the stone is cut en cabochon in such a way that the base is parallel to the fibres. A chatoyant Opal may otherwise be referred to as having a rolling-flash pattern, when the gem is rotated the cat’s eye glides over the face. Because Opal is predominantly cut en cabochon Cat's eye Opals are not the rarest occurence, though good examples with play of colour are hard to come by. rollingcatseyeboulder.jpg

Asterism: Created through reflection of light by thin fibrous or needle-like inclusions that lie in various directions. There are four rayed, six-rayed and twelve-rayed stars in Sapphires. However asterism is an extremely rare find in Opal, very few examples of Star Opals have been recorded, including three and six-rayed stars. Sometimes rare patterns may be termed 'Star' or 'Windmill' pattern, these are not neccesarily the same phenomena, they are usually more static with broader grains (rays) and a central point which does not move upon rotation of the stone.

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Detection of Enhanced & Man-made Opal Stones:

Treated Opals: Include Andamooka Matrix and Sandstone Opal from Queensland, referred to by the miners as Fairystone.

• Never transmit light and may be detected by their porosity, lower hardness and lower density (SG 1.98-2.05). Under magnification tiny black spots can be seen in the surface colour of these stones and poorly treated examples may show patches of colour.

Composites: Doublets & Triplets

triplet_in_profile_opal• Generally easily detected by inspection of the girdle area. Triplets are detectable when viewed from the side by the transparency of the quartz cap and planes of seperation and coloured cement may be visible.

Detection of Simulants:

Natural: Some multicoloured stones may appear like Opal to the untrained eye.
• Labradorite feldspar (definite cleavage and banded twinning)
• Ammolite (Fossil inverterbrate reminiscent of Black Opal also used in composites RI 1.52-1.67, SG 2.78)
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  • Imitation: Opal can be confused with Glass and some plastic imitations.
    • Glass (aka. paste) is simply imbedded with iridescent foil or as a doublet using opalescent (milky) glass. These are easily detected on sight or with the use of a loupe.
    • Plastic Simulants can be similar to Gilson in appearance, yet contain substances not found in natural Opal and are much lower in density, hardness and SG. These simulants are often highly porous and have a waxy texture.
  • Synthetic: ‘Gilson’ black and white Opals have all of the gemmological properties of natural Opal and are also heat resistant. There are several points of detection for this man made product:
    • Freedom of inclusions like potch or sand, and a stone which looks too perfect.
    • Gilson White Opal does not fluoresce under UV light unlike most natural white Opal. After Longwave UV is turned off the synthetic material phosphoresces for a much shorter time than natural Opals.
    • Very regular patterns and play of colour, with colours always arranged in uniform layers on vertical columns. Under magnification a mosaic pattern can be seen wihin each patch of colour, this can also be described as resembling a ‘snakeskin’ pattern.

Sources & Image Credits:

AUSTRALIAN PRECIOUS OPAL, Andrew Cody, 1991; Diagram: Refraction Grating of Light

Emil Weis Opals Collection; Photo of Opal Cats-eye

GEMSTONES OF THE WORLD, Walter Schumann, 1976; diagram: Moh's Hardness scale

HANDBOOK OF GEMSTONE IDENTIFICATION, Richard T. Liddicoat, Jr., 1990

OPAL IDENTIFICATION AND VALUE, Paul B. Downing PhD., 2001. (Photo of Star Opal)

THE Opaline COLLECTION; Photo of 'Spellbound' Boulder Opal Splits

Opal Module, GAA course notes, Anthony G. Smallwood, 1998.

 

Evaluation of Opal

Opal is a complex stone to evaluate and this task falls mainly in the hands of experts with years of experience.

There are many more facets to an Opal than the 4C's (Colour, Clarity, Cut, Carat) used to grade a Diamond.

The factors outlined below provide a concise guide to the foremost influences on an Opals value:

3 Varieties of Natural Opal:

Variety or Type alone does not affect price.

Light Opal

Boulder Opal

Black Opal

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Body Tone is the first point of price differentiation; a dark to black background is generally more desirable than a grey or milky-white background. In terms of diaphaneity a transparent/translucent stone will usually be more desirable than an opaque white stone.

Opal Nomenclature Body Tone Scale

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Brilliance of colours is of paramount importance – the brightness of an Opal is directly related to price.

Few stones display a brilliant full face of colour throughout 360 degree rotation, some need to be tilted to be appreciated, this is known as directionality. Most stones look best from one particular orientation whereas the finest Opals are non-directional.

Consistency of brilliance, and the density of a stone's body tone, whether it varies over the whole face of the Opal must also be considered.

Estimating the proportion of colour on the stone's face, averaged with the intensity of the colours emitted, one of three categories can be selected: 30%=Subtle, 30-70%=Bright, 70%(+)=Brilliant.

Pattern is almost as important and when combined with brilliance may increase price manyfold. Generally a larger pattern is more valuable than a smaller pattern Eg. ‘Harlequin’ is the most highly prized pattern whereas ‘Pinfire’ is a more common pattern. The descriptions may be termed otherwise, eg.'Broadflash' may be called 'Peacock' pattern, and the 'Cat's Eye' phenomenon is usually referred to as 'Rolling Flash' by the Opal trade.
A vivid pattern is more valuable than a static less playful one. A lively stone posses depth or saturation of colour and pattern.

peacockpattern.jpgbroadflash

straw.jpg

chaff/straw

ribbon.jpgribbon cats_eye_rolling_flash.jpgrollingflash
floral.jpgfloral

blue.jpgstraw (all blue)

harlequin.jpgharlequin

pinfire_pattern.jpgpinfire

flagstone.jpgflagstone peacockfloral.jpgribbon & floral hexagonal.jpghexagonal harlquin scan0029.jpgchinese writing

While every Opal has a unique pattern, there are seven categories of patterns that all Opals fit within: Pinfire, Flash, Broad Flash, Rolling Flash, Harlequin, Rare Patterns and Picture Stones. Over 90% of stones have Flash and Broad Flash patterns.


Colours present from the spectral range (Red, Orange, Yellow, Green, Indigo, Violet) may significantly affect an Opal’s value.

Red is the rarest and most valuable colour. Opals displaying red may potentially display all of the spectral colours, and if so they are referred to as ‘multicoloured’.

Bearing in mind that absolute value depends on brilliance, pattern and body tone; red and multicoloured Opals are rarer than green-orange, blue-green and blue Opals in that order. Given all other factors are equal an Opal containing red can be valued greater than a blue-green-yellow Opal by a factor of up to 3 times.

Sometimes the dominant colours in an Opal are referred to with the post script ‘–fire’ eg. green-fire or multi-fire.

Shape is most often dictated by the rough form. Most Opals, particularly Black Opals, tend to be fashioned as ovals and because opal is cut ‘en cabochon’ or with a domed surface these features have traditionally been preferred for jewellery aesthetics and calibration purposes.

However, most Boulder Opals are cut as free shapes which can lend themselves to more distinctive designs. In the last decade there has been a strong trend towards cutting freeform 3-dimensional shapes from most gem quality Opal. By sculpting the rough, yield is maximised in terms of weight and spread, aesthetic talent can then be applied to balance the stone's lapidary design.

A stone with a domed surface will be more valuable than one with a flat or undulated surface. This is because the domed stone has more depth from which to emit play of colour.

Weight is measured in Carats (1carat=0.2 Grams; 1kg=5000carats).

Prices per carat are generally at their greatest for exceptional stones between 3 and 5 carats and up to about 10 carats, after which larger sizes may become less commercially viable for jewellery purposes and value per carat tends to decrease.

Some stones have been cut disproportionately, a stone may have been left too thick (heavy on the backside) relative to its spread or face area. Allowance should be made for this when determining the absolute value per carat.


Imperfections or Inclusions are not uncommon in the back of stones, generally these are small sand-spots and do not affect price drastically. However marks or cracks that are noticeable in the face of the stone will have a marked effect on the price of an Opal.

Visible inclusions may include; patches or lines of potch, 'webbing', 'sand spots', crystals of gypsum and Ironstone in the face of Boulder Opal.

'Windows' in Black or Boulder Opal where there is an inconsistent patch in the Opal's body or backing that allows light to enter through the back of the stone and so dilute its play-of-colour.

Poor cutting and polishing, in terms of finish and proportions will also significantly reduce a stones value.

 

Sources & Image Credits:

A Journey with Colour, Vol I & II, Len Cram (Photos: various patterns)

AUSTRALIAN PRECIOUS OPAL, Archie Kalokerinos, 1971.(Photos:Hexagonal Harlequin, Pinfire)

AUSTRALIAN PRECIOUS OPAL, Andrew Cody, 1991. (Photos: Brilliance Scale)

OPAL IDENTIFICATION AND VALUE, Paul Downing PhD., 2001.

Crystal, Boulder and Black Gems from the Opaline Collection

A New Era for Opal Nomenclature, Australian Gemmologist. 19, 486-496., Anthony G. Smallwood, 1997.

Opal Module, GAA course notes, Anthony G. Smallwood, 1998.

Australian Opal

Classification of Precious Opal

‘Play of Colour’ is a unique visual phenomenon which sets precious Opal apart from all other gemstones.

An Opal may display one or more, and sometimes all of the spectral colours. These colours are seen within the grains of a pattern.

As the stone is viewed from different directions, rotated and tilted, the colours of each grain may change or disappear.

Australian Opal

Three Varieties of Natural Australian Opal


Each variety is a classification determined by background colour or 'body tone' which unlike the spectral colours do not appear to originate from coloured lights within the Opal. Body tone is produced by the same mechanism that produces the colours in pigments and paint. Each variety of Opal may include several types as outlined:

Australian Opal
Light Opal has a body tone ranging from milky white to transparent. Light Opal is the most common variety found at most fields but mainly at Coober Pedy and in South Australia. White Opal gives the full colour array on an opaque background, whereas Crystal Opal is transparent to translucent without milkiness and has bright colour flashes suspended in its midst. Crystal is superior to white, grey and jelly. Jelly Opal exhibits a moderate play of colour within a transparent background.

(Types: white *(photo), grey, crystal, jelly)

Black Opal has a blue-black to dark grey body tone and is mainly found at Lightning Ridge in New South Wales. The dark background serves to highlight the colour-play of dramatic spectral flashes. Fine examples of this variety are the most expensive per carat and rival diamonds in price. Black Opal is found as what the miners call ‘Nobbies’, these are fossil replacements of corals or sponges. During its formation, the replacement of organic material by Silica resulted in carbonaceous material or impurities like titanium impregnating the mineral structure giving Black Opal its body colour.

(Types: solid black *(photo), black crystal, semi-black)
Australian Opal













Boulder Opal is found in south west and central Queensland and can be light or dark in appearance, it forms naturally within the veins of ironstone boulders.
Boulder Opal may display the same darkness and brilliance as gem Black Opal yet it is more affordable and is generally sold at one third of the Black Opal carat price.

Many unique examples of Boulder opal are encased in or intertwined with the Boulder mother stone creating ‘matrix’, ‘Yowah nuts’ and other interesting textures known as ‘picture’ or ‘fun stones’.

Australian Opal Types of Boulder Opals:

1) Boulder pipe

2)Black Boulder green-orange fire

3) Light Boulder Yowah Kernel

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boulder_opal_matrix.jpg 4) Black Boulder red fire

5) Gem Yowah Nut Opal split-sawn pair

6)Boulder opal matrix

7) Gem Boulder split pair

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Boulder Opal is very durable due to the ironstone backing the opal forms on, which the cutter retains and polishes during the lapidary process.

The water content in Boulder Opal is very low, it almost never cracks or crazes as it ages and is considered the most stable variety by many experts.

 

Treated Opals

Treated Opals include Andamooka Matrix and Sandstone Opal from Queensland, referred to by the miners as Fairystone, which is often stained or blackened to resemble black opal and may also be treated with plastic stabilizers to improve the finish. Since the 1950's miners have treated the rock in sugar solution then carbonizing it by gently heating in concentrated sulphuric acid. In the rough state it is a muddy-grey to orange porous rock and lacks fire, once treated this stone may be startling in quality. Carbon is deposited into its pores by a process involving soaking Opal impregnated various organic solutions and applying heat up to 500 degrees Celsius. The rough material is fairly massive in occurrence and has been found across all the Opal fields. It is relatively inexpensive and has versatile applications in jewellery, carvings, clock faces, mosaics, inlays in furniture, tiles, paint finishes etc.

Matrix or Sandstone Opal never transmits light and may be detected by its porosity, lower hardness and lower density (SG). Under magnification tiny black spots can be seen in the surface colour of these stones and poorly treated examples may show uneven patches of body tone.

 

Man-made Opal stones


Composites - Doublets & Triplets are made using a slice of Light Opal and adhering it to a backing of black potch, plastic or boulder.
These are not investment quality stones but generally cheap products aimed as souvenirs. They lack durability and exposure to moisture can result in the opal veneer separating from its’ backing.

doublets.jpg
Doublets are made by gluing a slice of Opal to a black backing which enhances the reflection of colours from the Opal.
triplets.jpg
Triplets are made by adding a magnifying crystal top to a thin opal doublet.

Composites are detectable if the stones’ edges are examined, definite layers can be seen, under magnification. But some Boulder Doublets may display an irregular join line. If a pin is heated with a naked flame and then pushed into the join line, it should penetrate easily as the backing which looks like ironstone is actually powdered ironstone in an epoxy resin.

Synthetic or Gilson black and white Opals have all of the gemmological properties of natural Opal. The discovery of the ordered sphere structure of precious opal led to its synthesis by Pierre Gilson in 1974. In 1980 Kyocera Corporation of Japan began producing Inamori black and white synthetic Opal. Russian manufacturers are also producing synthetics, however there are several points of detection for these man made products;
• Freedom of inclusions like potch or sand, and a stone which looks too perfect.
• Gilson White Opal does not fluoresce under UV light unlike most natural white Opal.
• Very regular play of colour, with colours always arranged in uniform layers on vertical columns may arouse suspicion. Under magnification this has the effect of resembling a ‘snakeskin’ or 'mosaic' pattern.

gilson_cutstone.jpggilson_under_magnification.jpg

 

Imitation Opals made simply by imbedding iridescent foil in opalescent (milky) glass date back to ancient times. These are easily detected on sight. Slocum Stone made of glass (SG 2.45, RI 1.49-1.515) was the best Opal imitation available until 1978 when the Japanese produced plasic simulants that are somewhat more convincing and similar to Gilson to look at. This material has the same refractive index (RI 1.45) as natural Opal however it is lower in density (SG<1.58), often highly porous with a waxy texture. plastic_imitation_opal.jpg

 

www.bolda.com.au - 100% NATURAL AUSTRALIAN GEMS & JEWELLERY

 

Sources & Image Credits:

WITHIN THE STONE, Bill Atkinson, 2004. (Photo.1: Phenomenal - Play of Colour)

THE Opaline COLLECTION, Exceptional White, Boulder & Black Opals

HANDBOOK OF GEMSTONE IDENTIFICATION, Richard T. Liddicoat, Jr., 1990